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Optimization of the Process for Obtaining Biodiesel from Seeds of Ricinus communis using Basic Heterogeneous Catalyst in Transesterification

Published by the American Society of Agricultural and Biological Engineers, St. Joseph, Michigan www.asabe.org

Citation:  Applied Engineering in Agriculture. 38(1): 193-206. (doi: 10.13031/aea.14731) @2022
Authors:   Jose Manuel González Fernández, Eliazar Aquino-Torres, Otilio Arturo Acevedo-Sandoval, Jaime Pacheco-Trejo, Francisco Prieto Garcia, Judith Prieto-Méndez
Keywords:   Barium carbonate, Castor oil, Eco-fuel, Ethanol, Seed.

Abstract. Castor bean (Ricinus communis) can be a high-demand crop for the production of biodiesel, an alternative biofuel similar to conventional diesel. The objective of the work has been to optimize the method of obtaining biodiesel from a “green technology” process, directly splitting the seeds of three macerated castor varieties, without prior extraction of the oil with n-hexane as is traditional. Also using low-cost heterogeneous basic catalysts, friendly to the environment. It has been shown that it is feasible to obtain biodiesel as an eco-fuel from castor beans directly, without prior oil extraction with the consequent saving of n-hexane solvent and the non-use of sodium hydroxide. It is feasible to substitute methanol for ethanol (less toxic and cheaper), and as a novel aspect, the use of BaCO3 as a heterogeneous catalyst, not reported in any reference of those consulted. Yield percentages ranging between 31% and 45% were obtained, comparable to those obtained from previous oil extractions. It was concluded that of the three varieties of castor bean evaluated, the variety HG-A-1 (collected in Atotonilco el Grande, Municipality of the State of Hidalgo) classified as IBEA type, is the one that presents the best results.

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