Click on “Download PDF” for the PDF version or on the title for the HTML version.


If you are not an ASABE member or if your employer has not arranged for access to the full-text, Click here for options.

Bio-Crude Production via Hydrothermal Liquefaction of Enteromorpha prolifera: Operating Condition Optimization and High-Resolution FT-ICR Mass Spectral Analysis

Published by the American Society of Agricultural and Biological Engineers, St. Joseph, Michigan www.asabe.org

Citation:  Transactions of the ASABE. 60(6): 1799-1806. (doi: 10.13031/trans.12422) @2017
Authors:   Jixiang Zhang, Cheng Qian, Baohui Jiang
Keywords:   Bio-crude, FT-ICR MS, Hydrothermal liquefaction, Response surface methodology.

Abstract. is one of the main species causing green tide. In this study, hydrothermal liquefaction of E. was carried out, and the operating conditions were optimized using response surface methodology. The results indicated that hydrothermal liquefaction at 295°C with 14% solids content produced the highest bio-oil yield of 18.4%. The higher heating value was 31.9 to 34.2 MJ kg-1 and almost monotonically increased with increasing reaction temperature. The energy recovery, carbon recovery, and nitrogen recovery of bio-crude were mainly dependent on yield rather than elemental composition as the investigated variables changed. The chemical composition of bio-crude was characterized by Fourier transform ion cyclotron resonance mass spectrometry. The acidic O-containing compounds were mainly O2 class compounds, namely hexadecanoic acid and octadecanoic acid. The basic N-containing compounds were mainly nitrogenous heterocyclic compounds with carbon numbers of 20 to 40 and high degrees of unsaturation.

(Download PDF)    (Export to EndNotes)