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Click on “Download PDF” for the PDF version or on the title for the HTML version. If you are not an ASABE member or if your employer has not arranged for access to the full-text, Click here for options. Scale-Up of Liquid Hydrocarbon Production using Gasified BiomassPublished by the American Society of Agricultural and Biological Engineers, St. Joseph, Michigan www.asabe.org Citation: 2012 Dallas, Texas, July 29 - August 1, 2012 121337524.(doi:10.13031/2013.41801)Authors: Jason Street, Fei Yu, Eugene Columbus, James Wooten Keywords: syngas, gasoline-range hydrocarbons, gasifier, gasification, gasoline, wood feedstock, polymerization, oligomerization, hydrocarbons, synthesis gas This study showed that liquid hydrocarbons could be successfully created while also effectively controlling temperature using a proportional-integral-derivative (PID) control system in a scaled-up reactor system. A stainless steel tube reactor that measured 2 feet long with a 1.689 inch inside diameter was used to conduct the experiments. Tests were run at a gas hourly space velocity (GHSV) of 500 h-1 (1.4 SLPM) with a catalyst bed volume of 175 mL (93.6g) and a bed height of 4.8 inches. Syngas was subjected to 330o C at 1000 psi, 300o C at 800 psi, 300o C at 600 psi, and 300o C at 500 psi; while the producer gas was tested at 300o C at 1000 psi. An iron-based bi-functional catalyst that converted the syngas to liquid hydrocarbons in one step was used with (Airgas) synthesis gas and producer gas composed of approximately 18% H2, 23% CO, 11% CO2, 2% CH4, and 46% N2. The similar mole percentages from the store bought syngas (Airgas syngas) was used to mimic the producer gas from our particular downdraft gasifier, but the producer gas included 1% O2. Results indicated that the hydrogen conversion ranged from approximately 71% to 85% for all the tests while the conversion of CO ranged from approximately 87% to 96%. The heat generated was able to be properly controlled, and liquid hydrocarbons were successfully created from the producer gas and the store bought syngas. (Download PDF) (Export to EndNotes)
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